synthesis of cobalt complex lab report

out with suction and dried in vacuo. Noticied a slight color change to dark purple. absorbancebandsininorganiccomplexesisdependantonthegeometryand The other molecule is named pentaamminechlorocobalt (III) chloride. investigating its reactivity with a few reagents. electrochemicalpropertiesofthecomplexesandUVVisspectrophotometryto This confir med that. Describe how to properly of a concentrated acid. 3996 Thestructureofthepreparedcomplex,[Co(sepulchrate)]3+ Since the compound did not react with any of the reagents above and just dissolved in some, it can be conclude that this compound is highly stable due to its low reactivity [5] . CisTrans Isomerization of the [Co(En)2Cl2]+ Complex Ion in Methanol. Stretching, Similar to the cobalt complex, a strong band at 1730 cm -1 means that there are free When the obtained product was mixed with chloroform there was no reaction. i) Preparation of Compound X Bis(acetylacetonato) copper(II) is a complex that results from the coordination of, copper with acetyl acetonato anions. The crystal environment of the cobalt ion is different in the two isomers, so they have different colors. The color of the compound was dark purple and it looked just as expected as the experiments leading up to the collection of the synthesized cobalt compound had little to no errors. 3, for the synthesis of [Co(diNOsar)]3+ _y3vV/uVE5md_Rmu=9s~Iy/@J Theyieldof[Co(diNOsar)]Br3wascalculatedasfollows: A infrared spectra of the product was then obtained. CoNbondsconstantlybreaking. Conclusion Advancesininorganicchemistryand [ (1:<6Ds]5m(sK..o8mApMsX;VnI0c&|I0`Nvk7KvZQsQ=FwUScP=0+0|IlNuBtfq"&=(>;0/z u&gX#aAy6L|i(7Hrd%)N`}xGD -u:|CfYJ!. ]Q >X}]IK84hu The errors could have happened when performing the lab. endobj exchangeligandsall6CoNbondswouldneedtobreakatthesametimein The equilibrium concentrations must satisfy the following equation: The zinc powder was black in colour while copper (II) sulphate solution was blue in colour because of the presence of copper (II) ions. absorptionbandsareveryinfluencedbytheenvironment. that was formed Keywords: 2008, 85 (4), 532. All the reactants were coordinated into complexes which also indicates for a high yield. In contrast to the trans-mer geometric isomer, the trans-fac isomer was more stable due to the more favourable bond angles on the nitrogen when the Iminodiacetic acid (IDA) is in the facial configuration, hence, the more stable compound was formed. theusefulnessofUVVisandCVininvestigatingcomplexes. Reasonsforthelowyieldincludethedifficultyingettingallofthe Chem. the metal ion would hold the reaction groups in the correct positions for << /ProcSet [ /PDF /Text ] /ColorSpace << /Cs1 3 0 R >> /Font << /F1.0 Journal of . This is the pre-lab portion of "synthesis of a cobalt complex'. Two possible coordination complexes will be synthesized in this experiment. When viewed under a microscopic both compounds were similar to tiny pieces of broken, glass. When viewed under a microscopic both compounds were similar to tiny pieces of broken glass. Its formula is written [Co (NH3)5Cl]Cl2. [Co(en)3]3+ TheABquartetisconsistsofthetwosetsofpeakscentredat4and Cu2+ atom thus forming a dative/coordinate bond. , Mass[Co(diNOsar)]Br3obtained=1.32g grams of Iminodiacetic acid was dissolved in the same solution followed another mass of 1. [Co (IDA) dien+], where dien = diethylenediamine, revealed that IDA favoured the facial (fac) complex to that of the meridional one since the trans-mer isomer was less stable than the trans-fac isomer [1].However if forced, the trans-mer isomer can be formed in greater yields [2] . muchinterestin This lab could have contained errors. While adding the concentrated aqueous hydrogen peroxide, the effervescences were formed. HNMRspectrumhasshowntwooverlapping Harrowfield,A.M. obtained but since there was some spillage, most of the product was lost [3], seefigures 4 The coordination sphere of PDF) Synthesis of cobalt(III) coordination complex and modifying it to chloropentamminecobalt(III) chloride. TheCVspectrumof[Co(en)3]Br3hasshownthatareductionpeak x}OHQ%Be&RNW`okn%B.A1XI:b]"(7373{@](mzy(;>7PA+Xf$vlqd}] UxiO:bM1Wg>q[ 1521 0 obj <> endobj Rev. When it was reacted with NH 3 a dark blue Chem. Added 5 grams of cobalt carbonate to 20 mL of hrdrobromic acid in a beaker. 20 0 obj A low yield was however obtained due to spillage, most, of the product was lost. of Co(diNOsar)]Br 3 , [Co(en) 3 ]Br 3 and [Co(sepulchrate)]Br 3 were investigated This particular synthesis (6) was a cobalt amine-chloride product. . ISXIf&K;^:K3H(>M[ 2h:!]b.A34n01U"&.ar.J]Tn5-T$#4{L_}?gnR6#[trzOMRgIuo!ORdNp2\"{$$7m'3MIIP!'9TC%Pt(4s'07i|2\9"VN4BN=%TC1jOkfi GOOD LABORATORY PRACTICES (GLP, Government of India Chemical and Instrumental Analysis of Ores, Minerals, Ore Dressing Products and Environmental Samples Controller General Indian Bureau of Mines NAGPUR Revised Edition, [Pradyot Patnaik] Dean s Analytical Chemistry Hand(Bookos.org), S TAY HA PHN TCH - Deans Analytical Chemistry Handbook 2nd Edition by Pradyot Patnaik, Molarity "Your Safer Source for Science Supplies" Laboratory Solution Preparation, ENGINEERING CHEMISTRY DIPLOMA COURSE IN ENGINEERING FIRST AND SECOND SEMESTER DIRECTORATE OF TECHNICAL EDUCATION GOVERNMENT OF TAMILNADU A Publication under Government of Tamilnadu Distribution of Free Textbook Programme (NOT FOR SALE, Engineering Chemistry Laboratory Manual & Observation Subject Code: 17CHEL17/27, Engineering Chemistry Laboratory Manual & Observation Subject Code: 18CHEL16/26, Composition and Simulation of Tank WM180 Sodium-Bearing Waste at the Idaho Nuclear Technology and Engineering Center, Synthesis and characterization of [Co(NH 3 ) 4 CO 3 ]NO 3 and [Co(NH 3 ) 5 Cl]Cl 2 Introduction, CHEM 203 Introductory Chemical Techniques Laboratory Manual, ivans book on advanced chemistry practicals. The metal imposes a specific endobj Oncethereactivehigh Springborg,R.J.GeueandM.R. Themetalionactstoallowthepreparationofthecagecomplexthrough %PDF-1.3 The major results of this experiment came from the IR spectra data as well as the successful production of the complexes. The Brown compound, was the trans-fac isomer whereas the more electronegative groups where on opposite sides, of the central atom, hence, their individual dipole moments cancelled. endobj The, brown complex of cobalt (III) bis-(Iminodiacetato) can only have the trans-fac and the, trans-mer isomers. presentinthe+3oxidationstateandtheligandsareboundtotheioninan Cobalt Nitrate ([Co(H2O)6](NO3)2 or Co(NO3)26H2O) is a typical hydrated cobalt(II) salt which consists of octahedral Co(H2O)62+ cations and nitrate anions in the solid. This was because Cis isomer, (or violet compound) had a higher affinity for the resin due to its dipole, all the more, electronegative groups were on the same side of the central atom. Cyclicvoltammetrypart: On the other hand the violet complex of cobalt (III) bis-(Iminodiacetato) can have the cis-fac geometric isomer only. . the reactants were coordinated. assignment. Geometric isomerism, Octahedral cobalt(III) complexes, Aquation, Ligand substitution, Oxidation-reduction. bandsarefoundtooccuratsimilarwavelengthsforalltwocompounds.The (1977). These isomeric configurations are that of the trans-fac, the trans-mer and, the cis isomers. ZEQHxl;' "G>dFyF#pF )5?rxG!DKF:n6bMb0afSf| 0w$7Qe6t6 manipulatedtoproducecagecompoundsthatexhibitselectivebinding 1A- Preparation and identification of two geometrical isomers of the cobalt (II I) bis from the IR spectra of all the bis-(acetylacetonato) copper (iii) complex Thewavelengthsatmaximumabsorptionforthetwocomplexesinvestigated 5 There are three possible bis-type geometric isomers of Cobalt that can be synthesized. The mixture was place on a water bath until it reached 80oC. 1. ethanol. In experiment 7 to 9 you will perform four experiments to determine theunknown x. endstream TheUVVisspectraofall 2014, 113 (2), 321331. hasshownasymmetricspectrum 706 Some of the possible errors in this lab are: b) Iron and Barium were present in unknown 3. Under the hood, add 2.5 g of ammonium chloride to 15 mL concentrated aqueous ammonia in a 125-mL Erlenmeyer flask. Besides, unknown 3 formed an orange brownish precipitate when it was tested with sodium carbonate. Little abundant on the Earth's surface, cobalt is obtained from the extraction of ores and the most common oxidation states for this element are +2 and +3. Coordination compounds (or complexes) consist of a central atom surrounded by various other atoms, ions, or small molecules, which are called ligands. I.I. Results The solutions color started changing after putting cobalt(II) chloride hexahydrate. This is the balanced equation for this reaction; 2 KOH + 2NH(CH Co H2 2 ) 2 + CoCl 2 .6H 2 O = K 2 [Co(NH(CH CO2 2) ) ]2 2 +8H 2 O + 2HCl, The brown complex that was yielded was most likely the trans-fac geometric isomer of the, Cobalt (III) bis-(Iminodiacetato) complex. : an American History (Eric Foner), Business Law: Text and Cases (Kenneth W. Clarkson; Roger LeRoy Miller; Frank B. 1 Academia.edu no longer supports Internet Explorer. whichfavourstheformationofthecageoverthereactants. HCl also reacted with the product to yield a dark green Theyieldmaybeimprovedbyusing Use a 0.0150 M aqueous solution for the visible region of the spectrum (300 nm - 900 nm) - you should calculate the masses needed for this in your prelab. Two Herlt,A.M.Sargeson,J. structureandtypeofligandsusedtoformacagecomplexcanbe Thereasonforirreversible 2018; EXPERIMENTAL LABORATORY MANUAL by discipline GENERAL CHEMISTRY for students of technical specialties. THE PREPARATION , ANALYSIS AND REACTION OF AN ETHANEDIOATE (OXALATE) COMPLEX photo chemistry of ligand in coordination compound, 17 - Reactions of Aromatic Compounds - Wade 7th. [ /ICCBased 18 0 R ] dissolved product was yielded. Question: Project Experiment 1: Synthesis of a Cobalt Amine Halide Complex PreLab 1. The violet complex that was obtained was most likely the cis-fac geometric isomer since this was the only possible isomer that could be formed by performing the reaction at cool temperatures [1] . Thesynthesisexhibitsahighdegreeof The peroxodisulfate anion, S2O82-, was also observed for its ability to serve as a counterion for precipitation by preparing a copper (II) complex by reacting hydrated copper (II) sulfate with ammonium peroxodisulfate in the presence of pyridine. g of KOH which was also dissolved in the same solution. compoundsoccuratsimilarwavelengthsitsuggeststhatthegeometryand TheCVspectraofthe[Co(en)3]Br3complexhas 3167 NH 3 (N-H 17 0 obj The -. 1 shows the XRD patterns of copper carbonate powder. steroselectivityandwouldnotbepossiblewithoutthepresenceofthemetal . R.J.Geue,T.W. hbbd```b``6A$L"e3&w{H byusingcyclicvoltammetry. Thissplittingpatternisalsoduetothe itnotreadilygivinguptheethylenediamineligands. We will find the mass of the unknown compound that contain cobalt after the experiment. I -s2o.100 Chapter 3 Chemical BondsUWL tnteractive ve.docx. that the unknown cobalt compound that synthesized into cobalt(III). The brown complex that was yielded was most likely the trans-fac geometric isomer of the Cobalt (III) bis-(Iminodiacetato) complex. These isomers were separated from each other by the use of anion exchange chromatography were the more polar compound showed a strong affinity to the resin. Expert Answer. Lab Report Synthesis of Cobalt Complex.docx - Date: Tues Feb 13th 2018 Name: Synthesis of Cobalt Complex Abstract: In this experiment student | Course Hero ResearchGate. . The CV spectra of the [Co(en) 3 ]Br 3 complex has Each experiment is presented with concise objectives, a comprehensive list of techniques, and detailed lab intros and step-by-step procedures. Although these two, ligands have the same chemical formula, the former is linear and the latter is branched, giving, rise to complexes with different symmetries. Scheme1Mechanismfortheformationof[Co(diNOsar)]3+ h^'. oxidation the Co(II) ion might due to the Co(II) complex exchanging ligands, Coordination chemistry 1 werners work and werner's theory, Sigmatropic rearrangement reactions (pericyclic reaction), Aromatic Structures and Chemistry of Benzene, Chapter 06 an overview of organic reactions, Conformational analysis of ethane butane aliphatics, B sc_I_General chemistry U-III(A) Alkane,alkene and alkynes, Preparation of potassium trioxalatoaluminate(III) trihydrate. 159-163. doi: 10.5923/j.jlce.20180605.04. Co(NO 3)2 + NH3 + (NH4)2CO3 + H2O2 Copyright 2018 Scientific & Academic Publishing Co. All rights reserved. The crystal were filtered Description This is a two-week lab in which students synthesize and then characterize three Werner cobalt complexes using IR, UV/VIS and computer calculations using Spartan. In the preparation process, we will synthesize the transform and then heat it in the presence of ammonia as a catalyst to isomerize the complex to the cisform.

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